Rational addition of capping groups to the phosphomolybdate Keggin anion [PMo12O40](3-) by mild, non-aqueous reductive aggregation |
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| Authors: | Bakri Ridla Booth Andrew Harle Gavin Middleton Paul S Wills Corinne Clegg William Harrington Ross W Errington R John |
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| Institution: | School of Chemistry, Bedson Building, Newcastle University, Newcastle upon Tyne, UK. |
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| Abstract: | Controlled reductive assembly of capped Keggin anions PMo(12)O(40)(ML(m))(n)](3-) has been achieved by reduction of PMo(12)O(40)](3-) with sodium-mercury amalgam in the presence of metal halides, as exemplified by the rational syntheses of mono-capped PMo(12)O(40){Co(MeCN)(2)}](3-) and bi-capped PMo(12)O(40)(VO)(2)](3-) and PMo(12)O(40)Sb(2)](3-). |
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