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Correlation between i.r. spectra and thermal decomposition of cobalt(II), nickel(II), copper(II) and mercury(II) complexes with piperidinedithiocarbamate and pyrrolidinedithiocarbamate
Authors:Cavalheiro  Éder T G  Ionashiro  Massao  Marino  Glimaldo  Breviglieri  Susete T  Chierice  Gilberto O
Institution:(1) Depto. Química, UFSCar, São Carlos, São Paulo, CP 676, CEP 13565-905, Brazil;(2) Instituto de Química, UNESP, Araraquara, São Paulo, CP 355, CEP 14800-900, Brazil;(3) Inst. de Química de S. Carlos, USP, São Carlos, São Paulo, CP 780, CEP 13560-970, Brazil
Abstract:The thermal decomposition of pyrrolidinedithiocarbamate and piperidinedithiocarbamate complexes of CoII, NiII, CuII and HgII have been studied by thermogravimetry and differential scanning calorimetry. The decomposition intermediates and final products were identified by their X-ray diffraction patterns. The i.r. spectra are discussed in terms of the thermal decomposition pathways.
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