Aromatic hydrocarbon-catalyzed direct reaction of sulfur and sodium in a heterogeneous system: selective and facile synthesis of sodium monosulfide and disulfide |
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Authors: | Takata Toshikazu Saeki Daisaku Makita Yoshimasa Yamada Nobuo Kihara Nobuhiro |
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Institution: | Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan. takata@chem.osakafu-u.ac.jp |
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Abstract: | Sodium disulfide and monosulfide were selectively formed via the direct reaction of sulfur and an equimolar amount of sodium in 1,2-dimethoxyethane at 70 degrees C in the presence of a catalytic amount of aromatic hydrocarbons and ketone. |
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