Mild rhodium(III)-catalyzed C-H activation and intermolecular annulation with allenes |
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| Authors: | Wang Honggen Glorius Frank |
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| Institution: | Universit?t Münster, Organisch‐Chemisches Institut, Corrensstrasse 40, 48149 Münster (Germany) http://www.uni‐muenster.de/Chemie.oc/glorius/index.html |
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| Abstract: | All(enes) great! A novel Rh(III)-catalyzed oxidative coupling with allenes under mild conditions provides heterocycles with exocyclic double bonds. This reaction features low catalyst loadings, high regio- and stereoselectivity, and excellent substrate scope. The products were derivatized and preliminary mechanistic studies were conducted. |
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| Keywords: | 3 4‐dihydroisoquinolin‐1(2H)‐ones allenes C?H activation heterocycles rhodium |
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