W(bipy)(CN)6]-: a suitable metalloligand in the design of heterotrimetallic complexes. The first Cu(II)Ln(III)W(V) trinuclear complexes |
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| Authors: | Alexandru Maria-Gabriela Visinescu Diana Madalan Augustin M Lloret Francesc Julve Miguel Andruh Marius |
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| Affiliation: | Inorganic Chemistry Laboratory, Faculty of Chemistry, University of Bucharest, Str. Dumbrava Rosie 23, 020464 Bucharest, Romania. |
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| Abstract: | The first 3d-4f-5d heterotrimetallic complexes using [W(V)(bipy)(CN)(6)](-) as a metalloligand were synthesized (bipy = 2,2'-bipyridine). The structural and magnetic properties of three [Cu(II)Ln(III)W(V)] complexes (Ln = Gd, Ho, Tb) are discussed. |
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