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Fullerene/cobalt porphyrin hybrid nanosheets with ambipolar charge transporting characteristics
Authors:Wakahara Takatsugu  D'Angelo Pasquale  Miyazawa Kun'ichi  Nemoto Yoshihiro  Ito Osamu  Tanigaki Nobutaka  Bradley Donal D C  Anthopoulos Thomas D
Affiliation:Fullerene Engineering Group, Advanced Materials Processing Unit, Advanced Key Technologies Division, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan. Wakahara.takatsugu@nims.go.jp
Abstract:A novel supramolecular nanoarchitecture, comprising C(60)/Co porphyrin nanosheets, was prepared by a simple liquid-liquid interfacial precipitation method and fully characterized by means of optical microscopy, AFM, STEM, TEM, and XRD. It is established that the highly crystalline C(60)/Co porphyrin nanosheets have a simple (1:1) stoichiometry, and when incorporated in bottom-gate, bottom-contact field-effect transistors (FETs), they show ambipolar charge transport characteristics.
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