Intermolecular cross-double-michael addition between nitro and carbonyl activated olefins as a new approach in C-C bond formation |
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Authors: | Sun Xiaohua Sengupta Sujata Petersen Jeffrey L Wang Hong Lewis James P Shi Xiaodong |
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Affiliation: | C. Eugene Bennett Department of Chemistry, West Virginia University, Morgantown, West Virginia 26506, USA. |
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Abstract: | A novel intermolecular cross-double-Michael addition between nitro and carbonyl activated olefins has been developed through Lewis base catalysis. The reaction took place with a large group of beta-alkyl nitroalkenes and alpha,beta-unsaturated ketone/esters, producing an allylic nitro compound in good to excellent yields. |
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