Umsetzungen von Metall- und Metalloidverbindungen mit mehrfunktionellen Molekülen, 16. Mitt. |
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Authors: | Walter Maringgle Anton Meller |
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Institution: | (1) Anorganisch-Chemisches Institut, Universität Göttingen, D-3400 Göttingen, Bundesrepublik Deutschland |
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Abstract: | The reaction of trimethylsilylcarbonamides with halogeno-diorganyl-boranes resp. trihalogenoboranes or organodihalogenoboranes gives monomeric resp. dimeric amidoboranes (borylcarbonamides) and derivatives of 4,8-diaza-1,5-dibora-2,6,9-trioxabicyclo3.3.1]nonadienes. By reaction of the free acylamides with halogenoboranes in most cases the imide halides could be isolated as the only products. By reaction of the hydrochloride of bis(dimethylamino)-hydroxyborane withn-butyl-lithium followed by addition of the imide halides, the corresponding imidoylamines were formed.1H,11B, and19F-nmr spectra, mass spectra and characteristic ir group frequencies are reported.15. Mitt.:W. Maringgele undA. Meller, Z. anorg. allg. Chem., im Druck. |
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Keywords: | Amidoboranes Borylcarbonamides Imide halides NMR 11B NMR 19F |
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