X-ray crystallographic and physical investigation of tricyanomethanide and dicyanamide complexes of cobalt(II) with imidazole and its methyl derivatives |
| |
Authors: | Mária Hvastijová Jozef Ko?ísek Ji?í Kohout Lothar Jäger Hartmut Fuess |
| |
Institution: | (1) Department of Inorganic Chemistry, Slovak Technical University, 81237 Bratislava, Slovakia;(2) Fachbereich Chemie, Martin-Luther-University Halle-Wittenberg, 06120 Halle/Saale, Germany;(3) Fachbereich Materialwissenschaft Technische Hochschule Darmstadt, Petersenstra e 20, D-64287 Darmstadt, Germany |
| |
Abstract: | Summary Reaction of CoII with N(CN)
inf2
sup–
or C(CN)
inf3
sup–
in the presence of imidazole (iz) or its methyl derivatives (2-meiz and 4-meiz) gave eight compounds of CoII: ligand stoichiometry 1 2, including two isomeric pairs ( and ) for the complexes Co{C(CN)3}2(2-meiz)2] and Co{C(CN)3}2-(4-meiz)2]. The complexes were studied by electronic and i.r. spectroscopies. For -Co{C(CN)3}2(2-meiz)2] singlecrystal X-ray analysis was performed; its crystal structure consists of one-dimensional chains, formed by C(CN)
inf3
sup–
anions bridging between the CoII atoms. The CoII atom is nearly octahedrally coordinated by two tertiary nitrogens of 2-meiz and four nitrogens of C(CN)
inf3
sup–
. The spectra of these compounds and of the complexes with iz, as well as that of -Co{C(CN)3}2(4-meiz)2], indicate all these compounds to have basically the same bridging polymeric octahedral structure. However, the spectra indicate distorted tetrahedral structures for the remaining compounds. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|