Reaction of palladium bisacetylacetonate with elemental phosphorus. Effect of water on the composition of palladium phosphides |
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| Authors: | L. B. Belykh N. I. Skripov L. N. Belonogova A. V. Rokhin F. K. Shmidt |
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| Affiliation: | (1) Irkutsk State University, ul. K. Marksa 1, Irkutsk, 664003, Russia |
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| Abstract: | Reaction of palladium bisacetylacetonate with elemental phosphorus in an inert atmosphere is shown to proceed as a redox process forming palladium phosphides of different compositions: PdP2, Pd5P2, Pd4,8P, and Pd12P3,2. The conversion of Pd(acac)2 and the composition of palladium phosphides formed in benzene is established to be affected by water. A tentative scheme of the formation of palladium phosphides is suggested. |
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