| 用数字模拟方法研究耦联随后化学反应的表面可逆体系的循环伏安响应 |
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| 引用本文： | 王川,陈晓明,等.用数字模拟方法研究耦联随后化学反应的表面可逆体系的循环伏安响应[J].复旦学报(自然科学版),1993,32(1):1-7. |
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| 作者姓名： | 王川 陈晓明 |
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| 作者单位： | [1]1991届硕士研究生 [2]化学系 |
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| 摘 要： | 依照表面可逆反应的循环伏安响应原理，建立了有关的数字模型，给出不同的一级随后反应速度常数k1时的电流－极化曲线，讨论了该常数对循环伏安响应的影响及该常数的测定方法，并通过了对甲氧基偶氮苯吸附体系k1的测定，对理论模型进行了验证。
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| 关 键 词： | 数字仿真 循环伏安法 表面反应 |
DIGITAL SIMULATION OF CYCLIC VOLTAMMTRY OF SURFACE REVERSIBLE SYSTEM OF COUPLE FOLLOWING CHEMICAL REACTION |
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| Wang Chuan,Chen Xiaomin,He peixin.DIGITAL SIMULATION OF CYCLIC VOLTAMMTRY OF SURFACE REVERSIBLE SYSTEM OF COUPLE FOLLOWING CHEMICAL REACTION[J].Journal of Fudan University(Natural Science),1993,32(1):1-7. |
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| Authors: | Wang Chuan Chen Xiaomin He peixin |
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| Institution: | Department of Chemistry |
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| Abstract: | A digital model for cyclic voltammetry of reversible surface reaction has been built, the current-potential curves for first order following chemical reactions with various rate constants have been given, and the method for determining the rate constants and the influence of the rate constants to the resposibility of cyclic voltammetrv have been discussed. An experiment to determine the rate constants of p-methoxyazobenzene has been carried out for theoretical verification. |
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| Keywords: | digital simulation voltammetry cyclic voltammetry surface reaction following reaction |
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