A novel metal-free and metallophthalocyanines containing four 19-membered dithiadiazadioxa macrocycles by microwave irradiation: Synthesis and characterization |
| |
Authors: | Zekeriya B?y?kl?o?lu |
| |
Affiliation: | Department of Chemistry, Faculty of Arts and Sciences, Karadeniz Technical University, 61080 Trabzon, Turkey |
| |
Abstract: | The novel tetrasubstituted metal-free phthalocyanine (5) and metallophtalocyanines (6, 7 and 8) bearing four 19-membered dithiadiazadioxa macrocyclic moieties on peripheral positions have been synthesized by cyclotetramerization reaction of phthalonitrile derivative (4) in a multi-step reaction sequence. The new compounds were characterized by a combination of IR, 1H NMR, 13C NMR, UV-Vis, elemental analysis and MS spectral data. |
| |
Keywords: | Phthalocyanine Dithiadiazamacrocycle Phthalonitrile Macrocyclization Tosylation |
本文献已被 ScienceDirect 等数据库收录! |
|