Generation, isolation, and reactivity of a kinetically stabilized diphosphene anion radical |
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Authors: | Noriyoshi Nagahora Takahiro Sasamori Yukio Furukawa |
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Institution: | a Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan b Institute of Sustainability Science, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan c Department of Chemistry, School of Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku-ku, Tokyo 169-8555, Japan |
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Abstract: | The stable lithium diphosphene anion radical, Li(dme)3]+TbtPPTbt]− (dme: 1,2-dimethoxyethane, Tbt: 2,4,6-trisbis(trimethylsilyl)methyl]phenyl), was readily synthesized by the one-electron reduction of the corresponding neutral diphosphene (TbtPPTbt). The molecular structure of the diphosphene anion radical was discussed in detail on the basis of its ESR, UV-Vis and Raman spectra, and theoretical calculations. The diphosphene anion radical was found to undergo ready chalcogenation reactions using elemental sulfur and selenium to afford the corresponding thiadiphosphirane and selenadiphosphirane, respectively. |
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Keywords: | Diphosphene Cyclic voltammetry Reduction Anion radical UV-Vis spectrum ESR spectrum |
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