Reaction of methyl aluminium-(2,2′-methylene-p-chloro-bisphenoxide) with 2,2′-di(hydroxymethyl)biphenyl: A new aluminium complex bearing two kinds of diolate ligands |
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| Authors: | Wanda Ziemkowska Magdalena Metelska Romana Anulewicz-Ostrowska |
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| Institution: | a Warsaw University of Technology, Faculty of Chemistry, Koszykowa 75, 00-662 Warsaw, Poland
b Department of Chemistry, University of Warsaw, Pasteura 1, 02-093 Warsaw, Poland |
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| Abstract: | A reaction of Me3Al with 2,2′-methylene-p-chloro-bisphenol in Et2O yielded Me5Al3OC6H3(Cl)CH2C6H3(Cl)O]2 (1). Compound 1 reacted with 2,2′-di(hydroxymethyl)biphenyl to form Me3Al3OC6H3(Cl)CH2C6H3(Cl)O](OCH2C12H8CH2O)2 (2) bearing two kinds of diolate ligands. Compound 2 was structurally characterised. |
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| Keywords: | Aluminium Diols Alkoxides Bisphenoxides 2 2&prime -Di(hydroxymethyl)biphenyl |
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