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Synthesis of Schiff bases and benzylamino derivatives containing [1-B10H9NH3] anion
Authors:I. B. Sivaev  V. I. Bragin  V. I. Bregadze  N. A. Votinova  S. Sjoberg
Affiliation:(1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991 Moscow, Russian Federation;(2) M. V. Lomonosov Moscow Academy of Fine Chemical Technology, 86 prosp. Vernadskogo, 117571 Moscow, Russian Federation;(3) Department of Chemistry, Organic Chemistry, Uppsala University, P.O. Box 599, Uppsala, S-75124, Sweden
Abstract:Reactions of an amino derivative of the closo-decaborate anion [1-B10H9NH3] with aromatic aldehydes afforded Schiff bases [1-B10H9NH=CHAr] (Ar=Ph, C6H4-2-OMe, or C6H4-4-NHCOMe). The reduction of the latter with sodium borohydride gave the corresponding benzylamino derivatives [1-B10H9NH2CH2Ar].Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2004–2007, September, 2004.
Keywords:decahydro-closo-decaborate anion [B10H10]2–    Schiff bases  benzylamino derivatives
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