Synthesis of Schiff bases and benzylamino derivatives containing [1-B10H9NH3]− anion |
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Authors: | I. B. Sivaev V. I. Bragin V. I. Bregadze N. A. Votinova S. Sjoberg |
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Affiliation: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991 Moscow, Russian Federation;(2) M. V. Lomonosov Moscow Academy of Fine Chemical Technology, 86 prosp. Vernadskogo, 117571 Moscow, Russian Federation;(3) Department of Chemistry, Organic Chemistry, Uppsala University, P.O. Box 599, Uppsala, S-75124, Sweden |
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Abstract: | Reactions of an amino derivative of the closo-decaborate anion [1-B10H9NH3]– with aromatic aldehydes afforded Schiff bases [1-B10H9NH=CHAr]– (Ar=Ph, C6H4-2-OMe, or C6H4-4-NHCOMe). The reduction of the latter with sodium borohydride gave the corresponding benzylamino derivatives [1-B10H9NH2CH2Ar]–.Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2004–2007, September, 2004. |
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Keywords: | decahydro-closo-decaborate anion [B10H10]2– Schiff bases benzylamino derivatives |
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