Applicability of Friedman plot |
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Authors: | T Ozawa |
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Institution: | (1) Electrotechnical Laboratory, Sakura-Mura, Niihari-Gun, 305 Ibaraki, Japan |
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Abstract: | By expanding the initial equation, it is shown that the Friedman method for estimating the activation energy of chemical reactions by using both the conversion and the rate in the thermoanalytical data has wide applicability to crystal growth from pre-existing nuclei, diffusion and other processes in which a single unit process is involved.
Zusammenfassung Durch Erweiterung der ursprünglichen Gleichung wird gezeigt, daß die Friedman-Methode zur Bestimmung der Aktivierungsenergie chemischer Reaktionen unter Verwendung sowohl der Konversion als auch der Geschwindigkeit in thermoanalytischen Daten breite Anwendungsmöglichkeiten auf dem Gebiet des Wachstums von Kristallen aus Keimen, der Diffusion und anderer aus nur einem Grundprozeß bestehenden Vorgänge bietet.
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