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Two-dimensional nonlinear advection-diffusion in a model of surfactant spreading on a thin liquid film
Authors:Williams  H A R; Jensen  O E
Institution: 1 Department of Applied Mathematics and Theoretical Physics, University of Cambridge, Silver Street, Cambridge CB3 9EW
Abstract:The spreading of a localized monolayer of dilute, insoluble surfactant, discharged from a point source that moves at constant speed over a thin liquid film coating a planar substrate, is described according to lubrication theory by a pair of coupled nonlinear evolution equations for the monolayer concentration {Gamma}and the film depth h. Numerical and asymptotic techniquesare here used to show that the extent and structure of sucha spreading asymmetric monolayer can be well approximated bya single nonlinear advection–diffusion equation involving {Gamma}alone. At large times the solution is composed of three, spatiallydistinct, asymptotic regions: (i) a quasi-steady ‘nose’region (containing the source), in which there is a dominantbalance between two-dimensional nonlinear diffusion and advection;(ii) an ‘advective’ region, in which longitudinaladvection balances transverse diffusion; and (iii) a ‘tail’region, in which unsteady diffusion is dominant. In each region,local similarity solutions are obtained either exactly (inthe advective region) or approximately (elsewhere) by rescalingnumerical solutions of the initial-value problem. If the sourceconcentration decreases with time, it is demonstrated that the monolayer’s width is greatest in the tail region, whereasfor a source of increasing concentration the monolayer is widestin the advective region. For the simpler one-dimensional problemof a monolayer spreading from a line source, the same balanceshold but with transverse diffusion eliminated; here self-similarsolutions are found in all three regions that agree closelywith numerical solutions of the initial-value problem. Received 7 October, 1998. Revised 11 April, 2000. + antoine@mip.ups-tlse.fr § Present address: Division of Theoretical Mechanics, Schoolof Mathematical Sciences, University of Nottingham , UniversityPark, Nottingham NG7 2RD, UK. Oliver.Jensen@nottingham.ac.uk.
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