| 含混杂配体的Zn配合物的分子振动光谱研究 |
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| 引用本文： | 陈瑞平,郑瑜,王庆华,黄锦顺.含混杂配体的Zn配合物的分子振动光谱研究[J].光谱学与光谱分析,2000,20(6):847-848. |
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| 作者姓名： | 陈瑞平 郑瑜 王庆华 黄锦顺 |
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| 作者单位： | 结构化学国家重点实验室,中国科学院福建物质结构研究所,福建 |
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| 摘 要： | ＭＳ＾２－４（Ｍ＝Ｍｏ、Ｗ、Ｖ等）阴离子由于灵活多样的配位方式可形成特殊的构造单元而被广泛应用于分子设计中，本文对含有ＭＳ＾２－４及１，１０－ｐｈｅｎａｎｔｈｒｏｌｉｎｅ的混配金属配合物Ｚｎ（ｐｈｅｎ）２ＷＳ４和Ｚｎ（ｐｈｅｎ）２ＭｏＳ４的晶体进行红外光谱和拉曼光谱的研究并讨论了谱学与结构的关系。
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| 关 键 词： | 超分子化学 混配金属配合物 锌 分子振动光谱 |
Spectroscopy and Structure of the Zinc Complexes with Mixed Ligands |
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| R Chen,Y Zheng,Q Wang,J Huang.Spectroscopy and Structure of the Zinc Complexes with Mixed Ligands[J].Spectroscopy and Spectral Analysis,2000,20(6):847-848. |
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| Authors: | R Chen Y Zheng Q Wang J Huang |
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| Institution: | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002 Fuzhou. |
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| Abstract: | The negative ion,MS 2- 4(M=Mo,W,V ect.),is used widely in molecule designed as construction fragment because of its various ligand mode.The IR and Raman spectra of the crystals Zn(phen) 2WS 4 and Zn(phen) 2MoS 4 with mixed ligands MS 2- 4 and 1,10 phenanthroline have been investigated,and the coincidence between the spectrum and the structure has been discussed as well. |
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| Keywords: | IR spectrum Raman spectrum Complexes |
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