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Synthesis and Characterization of Novel Sulfonated Hybrid Congo Red Membranes from Chlorofunctionalized Silsesquioxanes for Fuel Cell Application
Authors:Ahmet Gültek  Yusuf Gökçen  Süleyman Köytepe  Turgay Seçkin
Institution:1. Inonu University, Faculty of Arts and Science Chemistry Department Malatya 44280 Turkey;2. Inonu University, Faculty of Arts and Science Biology Department Malatya 44280 Turkey
Abstract:A new sulfonated copolymers containing congo red groups were synthesized as a potential electrolyte for high temperature PEFCs. The resulting cross-linked sulfonated hybrid congo red membranes showed greatly improved water stability in comparison with the uncrosslinked ones while high proton conductivity was maintained. sulfonated membranes have been tested with respect to fuel cell performance. Short term fuel cell test for 100 hr gave a stable performance. These membranes are less expensive compared to Nafion. New sulfonated proton exchange composites membranes were used biological fuel cells. Molasses which is the waste of sugar factory, was used in anode as fuel and different bacteria species was sowing. Potential change was reported in biological fuel cells.
Keywords:congo-red  microbial fuel cell  PEM membrane  POSS
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