Mesoporous Molecular Sieves as Advanced Supports for Olefin Metathesis Catalysts |
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| Authors: | Hynek Balcar Jiří Čejka |
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| Institution: | J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, v.v.i., Dolejškova 3, 182 23 Prague 8, Czech Republic |
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| Abstract: | Summary: Siliceous mesoporous molecular sieves MCM-41, MCM-48 and SBA-15 and organised mesoporous alumina represent progressive supports for new heterogeneous catalysts for olefin metathesis and metathesis polymerization. In combination with Mo and Re oxides they provide catalysts of considerably higher activity in comparison with those based on conventional silica and alumina. Immobilization of Mo and Ru alkylidenes on these materials led to the highly active and selective catalysts with negligible leaching of transition metal. |
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| Keywords: | heterogeneous catalysts mesoporous molecular sieves olefin metathesis ring-opening metathesis polymerization transition metal catalysts |
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