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Thermophysical properties of binary liquid mixtures of polyether and n-alkane at 298.15 and 323.15 K: heat of mixing,heat capacity,viscosity, density and thermal conductivity
Affiliation:1. Bewag Aktiengesellschaft, Puschkinallee 52, 12435 Berlin, Germany;2. TU Berlin, Institut für Verfahrenstechnik, Sekr. TK 7, Str. des 17. Juni 135, 10623 Berlin, Germany;1. E. Hála Laboratory of Separation Processes, Institute of Chemical Process Fundamentals, The Czech Academy of Sciences, Rozvojová 135, 165 02 Prague 6 – Suchdol, Czech Republic;2. Institute of Chemistry, University of Silesia, Szkolna Street 9, 40-006 Katowice, Poland;3. CenTACat, School of Chemistry and Chemical Engineering, Queen’s University of Belfast, Stranmillis Road, Belfast BT9 5AG, United Kingdom;4. Department of Chemical Engineering & Biotechnology, Ariel University, 40700 Ariel, Israel;1. Drittes Physikalisches Institut, Georg-August-Universität, Friedrich-Hund-Platz 1, 37077 Göttingen, Germany;2. Institute of Chemistry, University of Silesia, Szkolna 9, 40-006 Katowice, Poland
Abstract:An apparatus for a rapid and simultaneous determination of the thermophysical properties excess enthalpy, isobaric heat capacity, kinematic viscosity, density and thermal conductivity has been developed. The experimental setup is subject of this paper. At 298.15 and 323.15 K, the systems ethylene glycol dimethyl ether–n-dodecane, diethylene glycol dimethyl ether–n-dodecane, triethylene glycol dimethyl ether–n-dodecane, tetraethylene glycol dimethyl ether–n-dodecane and diethylene glycol dibutyl ether–n-dodecane have been investigated. The experimental results are correlated and the macroscopic properties are interpreted.
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