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Synthesis and conversions of metallocycles. 8.13C NMR spectra of aluminocyclopentanes
Authors:R. R. Muslukhov  L. M. Khalilov  A. P. Zolotarev  A. B. Morozov  A. G. Ibragimov  U. M. Dzhemilev  G. A. Tolstikov
Abstract:Using13C NMR spectroscopy we have studied disubstituted and trisubstituted aluminocyclopentanes, determined the spectral parameters, and made stereochemical assignments of the isomers. The structure of the studied organoaluminum compounds has been confirmed by analysis of the products of hydrolysis, deuterolysis, and oxidation of aluminocyclopentanes.For communication 7, see [1].Institute of Organic Chemistry, Urals Branch, Russian Academy of Sciences, 450054 Ufa. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 9, pp. 2110–2116, September, 1992.
Keywords:organoaluminum compounds  NMR spectroscopy  stereochemistry  isomerism  molecular structure  chemical shift  hydrolysis  deuterolysis  oxidation
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