Fast stereoselective reactions in electrosprayed Co(II)/neurotransmitter nanodroplets |
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| Authors: | Fraschetti Caterina Aschi Massimiliano Filippi Antonello Giardini Anna Speranza Maurizio |
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| Affiliation: | Dipartimento di Studi di Chimica e Tecnologia delle Sostanze Biologicamente Attive, Università di Roma La Sapienza, Rome, Italy. |
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| Abstract: | Collision induced dissociation (CID) of the m/z 479 ion, formed by ESI of Co(NO3)2-CH3OH solutions with either pure (1S,2S)-(+)-N-methylpseudoephedrine or its mixtures with (1S,2R)-(+)- or (1R,2S)-(-)-ephedrine, provides compelling evidence for fast, stereoselective reactions in Co(II)/neurotrasmitter(s) aggregates during solvent evaporation of the ESI droplets. |
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