Excess molar volumes and enthalpies for the binary systems propyl propanoate + o-xylene, m-xylene, and p-xylene at 298.15 K |
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Authors: | Montserrat Domínguez-Prez Julieta Jimnez de Llano Luisa Segade Oscar Cabeza Carlos Franjo Eulogio Jimnez |
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Institution: | Departamento de Física, Facultad de Ciencias, Universidade da Coruña, 15071, A Coruña, Spain |
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Abstract: | This paper reports excess molar enthalpies, HmE, and excess molar volumes, VmE, of the binary systems {propyl propanoate + o-xylene}, {propyl propanoate + m-xylene} and {propyl propanoate + p-xylene} at the temperature 298.15 K and atmospheric pressure, over the whole composition range. VmE was calculated from the experimental measurement of the corresponding densities, while HmE was measured directly. The excess magnitudes were correlated to a Redlich-Kister type equation. Finally, we will discuss the results of the three mixtures studied here and by comparison with other binary systems containing propyl propanoate and a benzene-based compound previously published. |
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Keywords: | Excess volume Excess enthalpy Propyl propanoate Xylene Benzene-based compounds |
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