| Synthesis of a New Rigid Bicyclic AMPP Ligand （TIAMPP） and Application in Asymmetric Hydrogenation |
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| 引用本文： | Da Chun GONG Ping WEI Hua ZHOU Xiong Liang WANG Ping Kai OUYANG. Synthesis of a New Rigid Bicyclic AMPP Ligand （TIAMPP） and Application in Asymmetric Hydrogenation[J]. 中国化学快报, 2005, 16(9): 1169-1172 |
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| 作者姓名： | Da Chun GONG Ping WEI Hua ZHOU Xiong Liang WANG Ping Kai OUYANG |
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| 作者单位： | [1]Nanjing University of Technology, College of Life Science and Pharmacy, Nanjing 210009 |
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| 基金项目： | We are very grateful to Prof. Zhang Sheng Yong for helpful discussions and direction of experiment technology at the beginning of the project. We thank Cao Fei, He Hong Hua, Li Jian Jiang and Qin Wei Min in our asymmetric catalytic group for their generous help. |
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| 摘 要： | The new rigid bicyclic AMPP（（S）-TIAMPP） has been synthesized from the corresponding Ticol and Ph2PCI. The application of （S）-TIAMPP in Rh-catalyzed asymmetric hydrogenation of α-dehydroamino acids derivatives has been examined. Up to 93% ee was obtained.
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| 关 键 词： | TIAMPP α－氨基酸 不对称合成 α β－去氢氨基酸衍生物 氢化反应 甘氨酸类似物 亲电反应 |
| 收稿时间： | 2004-11-01 |
Synthesis of a New Rigid Bicyclic AMPP Ligand (TIAMPP) and Application in Asymmetric Hydrogenation |
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| Da;Chun;GONG;Ping;WEI;Hua;ZHOU;Xiong;Liang;WANG;Ping;Kai;OUYANG. Synthesis of a New Rigid Bicyclic AMPP Ligand (TIAMPP) and Application in Asymmetric Hydrogenation[J]. Chinese Chemical Letters, 2005, 16(9): 1169-1172 |
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| Authors: | Da Chun GONG Ping WEI Hua ZHOU Xiong Liang WANG Ping Kai OUYANG |
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| Abstract: | |
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| Keywords: | (S)-TIAMPP synthesis asymmetric hydrogenation. |
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