Fluorous analogues of DMAP (F-DMAP): Reusable organocatalysts for acylation reaction |
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| Authors: | Julien Legros Benoit Crousse Danièle Bonnet-Delpon |
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| Institution: | Laboratoire BioCIS-CNRS, Faculté de Pharmacie, Univ Paris-Sud, Rue J. B. Clément, F-92296 Châtenay-Malabry, France |
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| Abstract: | A short and facile preparation of analogues of DMAP (F-DMAPs) labelled with fluorous chains is reported. These catalysts efficiently promote the acylation of alcohols with anhydrides (Ac2O, (i-PrCO)2O) and can be partially recovered and reused. The effectiveness of F-DMAP is similar to that of DMAP. |
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| Keywords: | 4-(Dimethylamino)pyridine 4-Pyrrolidinopyridine PPY Organocatalysis Fluorous tag |
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