Functionalized fluoroalkyl and alkenyl silanes: Preparations, reactions, and synthetic applications期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Functionalized fluoroalkyl and alkenyl silanes: Preparations, reactions, and synthetic applications

Authors:	Kenji Uneyama

Affiliation:	Department of Applied Chemistry, Okayama University, 3-1-1, Tsushima-Naka, Okayama, 700-8530, Japan

Abstract:	Preparations, reactions, and synthetic applications of functionalized fluoroalkyl and alkenyl silanes have been summarized. This review focuses mainly on the chemistries of (1) 1-substituted difluoromethylsilanes (XCF₂SiR₃), (2) 1-substituted 2,2-difluorovinylsilanes (CF₂CXSiR₃), (3) trifluoroisopropenyl, trifluoroacetimidoyl, and trifluoroacetyl silanes [CF₃C(SiR₃)X, XCH₂, NAr, O] and (4) other fluorinated alicyclic silanes.

Keywords:	Fluoroalkylsilane Fluoroalkenylsilane 1-Substituted difluoromethylsilanes 1-Substituted 2,2-difluorovinylsilanes Trifluoroisopropenylsilane Trifluoroacetimidoylsilane Trifluoroacetylsilane C 0" alt=" single bond" src=" http://cdn.els-cdn.com/sd/entities/sbnd" class=" glyphImg" >F bond activation Desilylation Defluorination
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