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A novel synthesis of trifluoromethyl fluoroformate from trifluoromethyl hypofluorite and carbon monoxide in the presence of fluorine gas |
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| Authors: | Libin Du |
| Affiliation: | a Department of Chemistry, The University of North Carolina, Chapel Hill, NC 27599, USA b Department of Chemistry, Clemson University, Clemson, SC 29634, USA |
| Abstract: | Trifluoromethyl fluoroformate is prepared through a radical reaction between CF3OF and CO initiated by elemental fluorine. The reaction could be integrated into a continuous synthesis process. This method represents a convenient synthesis of the title compound under mild condition. |
| Keywords: | Trifluoromethyl fluoroformate Synthesis Elemental fluorine Radical chain reaction Continuous synthesis |
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