Functional fluoro substituted tetrakis-metallophthalocyanines: Synthesis, spectroscopy, electrochemistry and spectroelectrochemistry |
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Authors: | Arma?an Günsel At?f Koca |
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Institution: | a Department of Chemistry, Sakarya University, 54140 Esentepe, Sakarya, Turkey b Chemical Engineering Department, Engineering Faculty, Marmara University, 34722 Göztepe, Istanbul, Turkey c Department of Chemistry, Faculty of Science, Hacettepe University, Beytepe Campus, Ankara 06532, Turkey |
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Abstract: | In this study, electron-withdrawing fluoro-functional ligand and its tetrakis 2,9,16,23-4-(2,3,5,6-tetrafluoro)-phenoxy-phthalocyaninatometal (II) complexes, (ZnPcOBzF16, CuPcOBzF16 and CoPcOBzF16) (Bz: benzene) which are organo-soluble have been prepared. Their structures were confirmed by elemental analysis, FT-IR, 1H NMR, UV/vis and MS (Maldi-TOF) spectral data. Electron-withdrawing fluorine atoms on 2,3,5,6-position of benzene at the peripheral sites increases the solubility of the tetrakis-metallophthalocyanines. The cyclic voltammetry and differential pulsed voltammetry of the complexes show that while CuPcOBzF16 and ZnPcOBzF16 give ligand-based reduction and oxidation processes, CoPcOBzF16 gives both ligand and metal-based redox processes, in harmony with the common MPc complexes. Spectroelectrochemical measurements confirm the assignments of the complexes. |
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Keywords: | Phthalocyanines Fluorine Electron-withdrawing Maldi-TOF Aggregation Spectroelectrochemistry |
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