Hydrosilylation of Vinylsiloxanes with Hydrosiloxanes in the Presence of Thermo- and Photoactivated Platinum(II) Phosphine Complexes |
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| Authors: | de Vekki D. A. Skvortsov N. K. |
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| Affiliation: | (1) St. Peterburg State Institute of Technology, St. Petersburg, Russia |
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| Abstract: | Catalytic properties of thermo- and photoactivated platinum complexes [Pt(R2R'X)2Cl2] (X = P, R = Me, R' = Ph; X = P, As, Sb, R = R' = Ph or Bu) in hydrosilylation of vinylsiloxanes with hydrosiloxanes were studied. The neutral ligands were ranked in terms of their effect on the activity of the catalysts. A mechanism of hydrosilylation was proposed. |
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