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| 含有脲桥结构的双酰肼衍生物的合成和杀虫活性研究 | |
| 引用本文： | 毛春晖,汪清民,欧晓明,黄润秋,陈莉,尚坚,毕富春.含有脲桥结构的双酰肼衍生物的合成和杀虫活性研究[J].有机化学,2006,26(1):60-64. |
| 作者姓名： | 毛春晖 汪清民 欧晓明 黄润秋 陈莉 尚坚 毕富春 |
| 作者单位： | 1. 南开大学元素有机化学研究所元素有机化学国家重点实验室,天津,300071;湖南化工研究院,国家南方农药创制中心湖南基地,长沙,410007 2. 南开大学元素有机化学研究所元素有机化学国家重点实验室,天津,300071 3. 湖南化工研究院,国家南方农药创制中心湖南基地,长沙,410007 |
| 基金项目： | 国家自然科学基金(No.20202005)，全国优秀博士学位论文作者专项资金(No.200255)资助项目. |
| 摘 要： | 经2,6-二氟苯甲酰基异氰酸酯(或异氰酸苯酯)与N-叔丁基-N-取代苯甲酰肼(或苯环上含有氨基的双酰肼化合物)反应得到一系列含有脲桥结构的双酰肼类化合物, 生测结果表明部分目标化合物具有好的杀幼虫活性. 例如, 化合物IIa和IIe, 药剂浓度为0.02%, 杀幼虫活性分别为95%和100%. |
| 关 键 词： | 双酰肼化合物 昆虫生长调节剂 脲桥 蜕皮 杀幼虫活性 |
| 收稿时间： | 03 1 2005 12:00AM |
| 修稿时间： | 07 18 2005 12:00AM |
Synthesis and Insecticidal Evaluation of N,N-DiacylhydrazineDerivatives Containing the Urea Linkage |
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| MAO,Chun-Hui,WANG,Qing-Min,OU,Xiao-Ming,HUANG,Run-Qiu,CHEN,Li,SHANG,Jian,BI,Fu-Chun.Synthesis and Insecticidal Evaluation of N,N-DiacylhydrazineDerivatives Containing the Urea Linkage[J].Chinese Journal of Organic Chemistry,2006,26(1):60-64. | |
| Authors: | MAO Chun-Hui WANG Qing-Min OU Xiao-Ming HUANG Run-Qiu CHEN Li SHANG Jian BI Fu-Chun |
| Institution: | a. State Key Laboratory of Elemento-organic Chemistry, Research Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071;b. Hunan Branch of National Pesticide Research and Development South Center, Hunan Research Institute of Chemical Industry, Changsha 410007 |
| Abstract: | A series of novel N,N'-diacylhydrazine derivatives containing the urea linkage were synthesized by the reaction of 2,6-difluorobenzoyl isocyanate (or isocyanatobenzene) with N-tert-butyl-N-substituted benzoylhydrazine or N,N'-diacylhydrazines containing amino group in 1,2-dichloroethane under reflux. The results of bioassay showed that some of the title compounds exhibit good larvicidal activities. For example, the larvicidal activities of derivatives IIa and IIe to Oritental armyworm at the concentration of 0.02% were 95% and 100%, respectively. |
| Keywords: | diacylhydrazine insect growth regulator urea linkage exuviation larvicidal activity |
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