Conductance of solutions of lithium bis(trifluoromethanesulfone)imide in water,propylene carbonate,acetonitrile and methyl formate at 25°C |
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Authors: | Mark Salomon |
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Affiliation: | (1) U. S. Army Electronics Technology and Devices Laboratory (LABCOM) Power Sources Division, 07703-5601 St. Monmouth, NJ |
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Abstract: | Conductance data for lithium bis(trifluoromethanesulfone)imide, LiN(CF3SO2)2, are reported for the solvents water, propylene carbonate, acetonitrile and methyl formate at 25°C. Limiting molar conductivitiesA0, association constants KA, and triple ion formation constants Kt are reported where applicable. These data are compared with literature data for the commonly studied lithium salts LiClO4 and LiAsF6. Non-coulombic energy contributions to ion pair formation are evaluated and discussed in terms of ion-ion and ion-solvent interactions. |
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Keywords: | Electrolyte conductance ionic conductance ion-pair formation triple ion formation non-coulombic interactions lithium salts bis(trifluoromethanesulfone)imide anion water propylene carbonate acetonitrile methyl formate |
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