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Highly regio- and stereoselective ring-opening of epoxides and aziridines with sodium azide using ammonium-12-molybdophosphate
Authors:Biswanath Das   Vtukuri Saidi Reddy   Maddeboina Krishnaiah  Yerra Koteswara Rao
Affiliation:

aOrganin Chemisry Division-I, Indian Institute of Chemical Technology, Hyderahad 500007, India

Abstract:Epoxides and aziridines undergo ring-opening readily with NaN3 in the presence of ammonium-12-molybdophosphate to afford the corresponding 2-azidoalcohols and 2-azidoamines in high yields with good regio- and stereoselectivity under mild reaction conditions.
Keywords:Epoxide   Aziridine   2-Azidoalcohol   2-Azidoamine   Ammonium-12-molybdophosphate   Regioselectivity
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