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Graft copolymers of polycaproamide with polyimide based on fluorene dianiline and 3,3′,4,4′-tetracarboxydiphenyloxide: Microstructure and properties
Authors:T V Volkova  O N Pashkova  M N Il’ina  E M Belavtseva  Ya S Vygodskii
Institution:(1) Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 117813, Russia
Abstract:It is established that graft copolymers of polycaproamide with 3–5 wt % of polyimide exhibit a rubber-like elasticity region above the polycaproamide melting temperature. Polycaproamide modification with polyimide increases the polymer thermal resistance, glass-transition temperature, and impact strength. Scanning electron microscopy revealed that the supramolecular organization of polycaproamide is similar to that of its copolymers with polyimide but differs in the spherulite size.
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