Graft copolymers of polycaproamide with polyimide based on fluorene dianiline and 3,3′,4,4′-tetracarboxydiphenyloxide: Microstructure and properties |
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Authors: | T V Volkova O N Pashkova M N Il’ina E M Belavtseva Ya S Vygodskii |
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Institution: | (1) Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 117813, Russia |
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Abstract: | It is established that graft copolymers of polycaproamide with 3–5 wt % of polyimide exhibit a rubber-like elasticity region above the polycaproamide melting temperature. Polycaproamide modification with polyimide increases the polymer thermal resistance, glass-transition temperature, and impact strength. Scanning electron microscopy revealed that the supramolecular organization of polycaproamide is similar to that of its copolymers with polyimide but differs in the spherulite size. |
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