静电场中Ca原子里德堡态的能级结构

用两步激发和光电离方法,在0—8kV/cm电场范围内,测定了Ca原子n=10至n=13附近m=0的Stark光谱。实验结果显示,3d²³P₀及3d²³P₂价态受到n=12Stark簇的排斥。观察到与价态有关的干涉现象及其随电场大小的改变。讨论了零场非简并态、价态及Stark簇之间的能级交叉和抗交叉结构。

LEVEL STRUCTURE OF THE RYDBERG STATES OF CALCIUM ATOM IN ELECTRIC FIELD

The Stark spectrum of Ca atom with m = 0 in the vicinity of n = 10 to n = 13 have been obtained by using two-step excitation and photoionization methods in the applied electric field from 0 to 8 kV/cm. The experimental results show that the 3d^{2 3}P₀ and 3d^{2 3}P₂ valence states are repelled by n= 12 Stark manifold. The interaction among the zero-field non-degenerate states, valence states and Stark states are discussed. The interference phenomenon, in which valence state and Stark states take part, has been observed. The interference is enhanced when the electric field increase.