Synthesis of α, β-unsaturated diketones and derivatives of Δ2-pyrazoline derived from 2, 5-diacetylthiophene |
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Authors: | S V Tsukerman Lam Ngok Thiem V M Nikitchenko V F Lavrushin |
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Institution: | (1) Gor'kii Khar'kov State University, USSR |
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Abstract: | The Claisen reaction of 2, 5-diacetylthiophene with various aromatic and heterocyclic aldehydes was utilized to prepare 15 new unsaturated diketones(diarylidene-2, 5-diacetylthiophenes). Most of them were characterized as their bis-2, 4-dinitrophenylhydrazones, for which
max values in chloroform solution are given. The reaction of diarylidene-2, 5-diacetylthiophenes with phenylhydrazine. hydrochloride has given five 2, 5-bis(1-phenyl-5-R-2-pyrazoline-3-yl) thiophene showing strong luminescence. A method was developed for the synthesis of 2, 5-diacetylthiophene by the oxidation of 5-ethyl-2-acetothienone. |
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