| 对苯乙烯磺酸在水滑石层间的柱撑及聚合 |
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| 引用本文： | 胡玉军,包永忠,黄志明,翁志学. 对苯乙烯磺酸在水滑石层间的柱撑及聚合[J]. 应用化学, 2006, 23(6): 672-0 |
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| 作者姓名： | 胡玉军 包永忠 黄志明 翁志学 |
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| 作者单位： | 浙江大学聚合反应工程国家重点实验室 |
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| 摘 要： | 对苯乙烯磺酸在水滑石层间的柱撑及聚合;水滑石;对苯乙烯磺酸;柱撑;聚合
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| 关 键 词： | 对苯乙烯磺酸在水滑石层间的柱撑及聚合 水滑石 对苯乙烯磺酸 柱撑 聚合 |
| 文章编号： | 1000-0518(2006)06-0672-04 |
| 收稿时间： | 2005-07-16 |
| 修稿时间： | 2005-10-30 |
Pillaring and Polymerization of Vinylbenzene Sulfonate in the Interlayer of Hydrotalcite |
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| HU Yu-Jun,BAO Yong-Zhong,HUANG Zhi-Ming,WENG Zhi-Xue. Pillaring and Polymerization of Vinylbenzene Sulfonate in the Interlayer of Hydrotalcite[J]. Chinese Journal of Applied Chemistry, 2006, 23(6): 672-0 |
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| Authors: | HU Yu-Jun BAO Yong-Zhong HUANG Zhi-Ming WENG Zhi-Xue |
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| Affiliation: | State Key Laboratory of Polymer Reaction Engineering, Zhejiang University, Hangzhou 310027 |
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| Abstract: | Vinylbenzene sulfonate(VBS) pillared hydrotalcite(VBS-HT) was obtained by the ion-(exchange) reaction of VBS with nitrate anion pillared HT(NO_(3)-HT),which was previously prepared by a co-precipitation method.The polymerization of pillaring VBS was conducted.The structure of VBS pillared HT and its(polymerization) product were characterized by means of X-ray diffraction,infrared spectrum and elemental(analysis).It was found that well pillaring of VBS in HT could be achieved via ion-exchange reaction,and the(interlayer) spacing increased from 0.90 nm for NO_(3)-HT to 1.83 nm for VBS pillared HT.The interlayer(spacing) was further increased to 1.94 nm after VBS was polymerized in the interspace of HT. |
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| Keywords: | hydrotalcite vinylbenzene sulfonate pillar polymerization |
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