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Growth of Hollow Transition Metal (Fe,Co, Ni) Oxide Nanoparticles on Graphene Sheets through Kirkendall Effect as Anodes for High‐Performance Lithium‐Ion Batteries
Authors:Xianbo Yu  Bin Qu  Yang Zhao  Chunyan Li  Prof Yujin Chen  Prof Chunwen Sun  Prof Peng Gao  Dr Chunling Zhu
Institution:1. Key Laboratory of In-Fiber Integrated Optics, Ministry of Education, and College of Science, Harbin Engineering University, Harbin, P. R. China;2. Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, Beijing, P. R. China;3. College of Chemistry and Chemical Engineering, Harbin Engineering University, Harbin, P. R. China
Abstract:A general strategy based on the nanoscale Kirkendall effect has been developed to grow hollow transition metal (Fe, Co or Ni) oxide nanoparticles on graphene sheets. When applied as lithium‐ion battery anodes, these hollow transition metal oxide‐based composites exhibit excellent electrochemical performance, with high reversible capacities and long‐term stabilities at a high current density, superior to most transition metal oxides reported to date.
Keywords:batteries  graphene  Kirkendall effect  nanoparticles  transition metals
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