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A simple synthesis of 4-substituted 2,3-benzoxazinones from C-2 arylated 1,3-indanediones
Authors:Suven Das  Pradyot KoleyAnimesh Pramanik
Institution:a Department of Chemistry, University of Calcutta, 92, A. P. C. Road, Kolkata 700 009, India
b Rishi Bankim Chandra College for Women, Naihati, North 24-Parganas 743 165, India
Abstract:A simple one-pot procedure for the conversion of 2-hydroxy-2-(2′-hydroxy-aryl)-1,3-indanediones to 4-substituted benzoxazinones has been developed. The process constitutes an interesting acid-catalyzed rearrangement followed by condensation with hydroxylamine.
Keywords:Ninhydrin  Hydroxylamine  2  3-Benzoxazinones  Acid-catalyzed reaction
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