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Synthesis and complex-forming properties of nitrogen-methylated ethylenediamino-N,N′-dimethyl- and ethylenediamino-N,N′-diethylphosphonic acids
Authors:T Ya Medved'  N M Dyatlova  V P Markhaeva  M V Rudomino  N V Churilina  Yu M Polikarpov  M I Kabachnik
Institution:1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow
2. Institute of Chemical Reagents and Very Pure Substances, Moscow
Abstract:
1.  New organophosphorus complexing agents were synthesized: ethylenediamino-N,N'-diethylphosphonic, N,Nprime-dimethylethylenediamino-N,Nprime-dimethylphosphonic, and N,Nprime-dimethylethylenediamino-N, Nprime-diethylphosphonic acids and also the iodomethylate of the last acid.
2.  The acid dissociation constants for these compounds and the stability constants for their complexes with nickel, copper, dysprosium, and uranyl ions were determined.
Keywords:
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