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RuCl3·3H2O Mediated Olefin Isomerizations in Ionic Liquids: A Highly Recyclable System for Olefin Isomerizations
Authors:SHAO Ming-bo  LIU Gui-yan  ZHAO Jing-jing  WANG Xiao-yu  WANG Jian-hui
Affiliation:1. Department of Chemistry, College of Science, Tianjin University, Tianjin 300072, P. R. China;
2. Tianjin Key Laboratory of Structure and Performance for Functional Molecule, College of Chemistry, Tianjin Normal University, Tianjin 300387, P. R. China
Abstract:Herein lies a convenient and highly efficient method of olefin isomerization in the presence of RuCl3·3H2O in ionic liquid(IL). More importantly, RuCl3·3H2O is a robust and recyclable catalyst. Nine cycles of RuCl3·3H2O as the catalyst were performed for the isomerization reactions of the selected substrate in IL and MeOH.
Keywords:Ruthenium trichloride  Ionic liquid  Olefin isomerization  
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