| 水合六硼酸钡的合成与热化学研究 |
| |
| 引用本文： | 黄宏升,李平. 水合六硼酸钡的合成与热化学研究[J]. 化学研究与应用, 2010, 22(2) |
| |
| 作者姓名： | 黄宏升 李平 |
| |
| 作者单位： | 安康学院化学化工系,陕西,安康,725000;陕西师范大学陕西省大分子科学重点实验室,化学与材料科学学院,陕西,西安,710061 |
| |
| 基金项目： | 国家自然科学基金,安康学院科研专项计划 |
| |
| 摘 要： | 硼原子的硼酸盐种类繁多,结构复杂多样,其中,有一些硼酸盐具有特殊的性能,如:2ZnO·3B_2O_3·3.5H_2O、2CaO·3B_2O_3·5H_2O可用作阻燃材料~([1]),β-BaB_2O_4(β-BBO)~([2])、Ba_2Be_2B_2O_7~([3])、BaAl_2 B_2O7_~([4])等因其具有良好的光学性质,被广泛用作非线性光学材料.因此,进行硼酸盐的合成及性质研究有着重要的意义.
|
| 关 键 词： | 六硼酸钡 热化学 标准摩尔生成焓 |
Synthesis and thermochemistry of hydrated barium hexaborate |
| |
| HUANG Hong-sheng,LI Ping. Synthesis and thermochemistry of hydrated barium hexaborate[J]. Chemical Research and Application, 2010, 22(2) |
| |
| Authors: | HUANG Hong-sheng LI Ping |
| |
| Abstract: | One new hydrated barium hexaborate has been prepared and identified by chemical analysis,X-ray diffraction(XRD),infrared spectral(IR)and thermal analysis(TG-DTG,DSC).The constitute of sample is BaB_6O_(10)·4.5H_2O.The structure and thermal decomposition process of sample were studied.The molar enthalpies of solution of BaB_6 O_(10)·4.5H_2 O in 1 mol·dm~(-3) HCl (aq)were measured in a series of experiments.With the incorporation of the previously determined enthalpy of solution of other substances in HCl(aq)and the standard molar enthalpies of formation of related substances,the standard molar enthalpies of |
| |
| Keywords: | barium hexaborate thermochemistry standard molar enthalpy of formation |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
