Influence of thermodynamic conditions of polymerization on supramolecular and molecular structure of the polymers

The problems of the formation of the supramolecular and molecular structure of polymers are considered. Based on kinetic investigations of trioxane polymerization, the thermodynamic approach to the problem of regulating the supramolecular and molecular structure of polymers during synthesis is formulated. A method for producing polymers with the given supramolecular structure is suggested. It is noted that the application of this method allows one to regulate the structure during the synthesis of three-dimensional cross-linked polymer systems as single-component, filled, reinforced, and other composite materials.