The first Pd(II) complex of a non-heteroatom stabilised carbene ligand |
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Authors: | Bröring Martin Brandt Carsten D Stellwag Sascha |
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Affiliation: | Fachbereich Chemie, Philipps-Universit?t Marburg, Hans-Meerwein-Strasse, D-35043 Marburg, Germany. Martin.Broering@chemie.uni-marburg.de |
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Abstract: | Di(p-tolyl)diazomethane reacts with the tripyrrinate TrpyPdOAc(F) 1 after activation with NaBAr(F) to yield the first stable Pd(II) complex 2 of a non-Arduengo type carbene ligand, which could be characterised by X-ray crystallography. |
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