Trinuclear and hexanuclear platinum clusters as building blocks for organometallic one-dimensional structures |
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Authors: | Leoni Piero Marchetti Fabio Marchetti Lorella Pasquali Marco |
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Institution: | Dipartimento di Chimica e Chimica Industriale, Via Risorgimento 35, 1-56126 Pisa, Italy. leoni@dcci.unipi.it |
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Abstract: | The reaction between the new hexa- and trinuclear clusters Pt6](CC-C6H4-CCH)2, (4) Pt6] = Pt6(CO)4(mu-PBu(t)2)4], and Pt3]Cl, (6) Pt3] = Pt3(mu-PBu(t)2)3(CO)2], in CuI/Amine gives the thermally and air stable Pt6](CC-C6H4-CCPt3])2 (7), where the cluster units are separated by conjugated 1,4-diethynylphenyl groups. |
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