Bright phosphorescence of a trinuclear copper(I) complex: luminescence thermochromism, solvatochromism, and "concentration luminochromism" |
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| Authors: | Dias H V Rasika Diyabalanage Himashinie V K Rawashdeh-Omary Manal A Franzman Matthew A Omary Mohammad A |
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| Affiliation: | Department of Chemistry and Biochemistry, The University of Texas at Arlington, Arlington, Texas 76019, USA. dias@uta.edu |
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| Abstract: | A photophysical study is reported for the trinuclear copper(I) complex {[3,5-(CF3)2Pz]Cu}3. The neutral compound exhibits multicolor bright phosphorescent emissions both in the solid state and in solution. The emission can be tuned to multiple visible colors by controlling the temperature, solvent, and {[3,5-(CF3)2Pz]Cu}3 concentration, giving rise to luminescence thermochromism, luminescence solvatochromism, and a new optical phenomenon called "concentration luminochromism", respectively. |
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