Poly(ruthenium carbonyl spirobifluorenylporphyrin): a new polymer used as a catalytic device for carbene transfer |
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| Authors: | Poriel Cyril Ferrand Yann le Maux Paul Paul Christine Rault-Berthelot Joëlle Simonneaux Gerard |
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| Affiliation: | Laboratoire de Chimie Organométallique et Biologique, UMR CNRS 6509, Université de Rennes I, 35042 Rennes cedex, France. |
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| Abstract: | Oxidative electropolymerization of tetraspirobifluorenyl porphyrin ruthenium(II) carbonyl complexes can be used to coat Pt electrodes with polymeric films; after being removed from the electrode, these polymeric materials are able to catalyze the heterogeneous cyclopropanations and 2,3 sigmatropic rearrangements with ethyl diazoacetate. |
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