NMRON studies of ferromagnetic hcp and fcc Co |
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Authors: | W D Hutchison A V J Edge N Yazidjoglou D H Chaplin |
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Institution: | (1) Department of Physics, University College, The University of New South Wales, Australian Defence Force Academy, 2600 Campbell, ACT, Australia |
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Abstract: | The high resolution hyperfine spectroscopy, modulated adiabatic passage of oriented nuclei (MAPON), has been applied for the
first time to high purity, elemental systems. Detailed comparisons between the electric quadrupole hyperfine interactions
(EQI’s) and, in particular, their distributions, are obtained for60CoCo where the hosts are a single crystal of hcp cobalt and a polycrystalline cobalt foil of predominantly fcc character. For
hcp Co, with the electronic magnetization, M, parallel to the c-axis, the mode value P/h=3e2qQ/4I(2I−1)h=−48.5(5) kHz. This fractional distribution implies the sharpest electric field gradient (efg) measured in a metal
to date, using MAPON spectroscopy, in excess of two times sharper than that of the most dilute impurity efg in a crystallographically
cubic ferromagnetic host. The mode efg is Vzz=−27.3(32)×1019 Vm−2. For the polycrystalline, predominantly fcc foil, prepared by quenching, the EQI mode value is P/h=−6.2(4) kHz with a FWHM
of 12.0(7) kHz yielding a mode efg of Vzz=−3.5(5)×1019 Vm−2. |
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