| 离子液体谱学性质和热力学数据关联的新进展 |
| |
| 引用本文： | 许映杰,朱霄,李浩然. 离子液体谱学性质和热力学数据关联的新进展[J]. 中国科学:化学, 2014, 0(6): 877-888 |
| |
| 作者姓名： | 许映杰 朱霄 李浩然 |
| |
| 作者单位： | [1]绍兴文理学院化学系,绍兴312000 [2]曲阜师范大学化学化工学院,曲阜273165 [3]浙江大学化学系,杭州310027 |
| |
| 基金项目： | 国家自然科学基金（21206085）、浙江省科技创新团队项目（2011R50007）、中央高校基础科研基金和浙江省自然科学基金（Y4090453）资助,特此一并致谢. |
| |
| 摘 要： | 离子液体的性质是其微观结构和相互作用的外在表现,与其应用密切相关.谱学手段能从分子水平上探测离子液体的微观环境和相互作用,近年来在定量关联或预测离子液体宏观性质方面发挥着越来越重要的作用.本文着重概述了红外光谱(IR)、拉曼光谱(Raman)、核磁共振波谱(NMR)和电子顺磁波谱(ESR)等常见谱学手段在定量关联离子液体及其溶液体系宏观性质方面的研究进展以及发展方向.
|
| 关 键 词： | 离子液体 热力学性质 谱学性质 关联 |
New progress in relationships between the spectroscopic and thermodynamic properties of ionic liquids |
| |
| XU YingJie,ZHU Xiao,LI HaoRan. New progress in relationships between the spectroscopic and thermodynamic properties of ionic liquids[J]. Scientia Sinica Chimica, 2014, 0(6): 877-888 |
| |
| Authors: | XU YingJie ZHU Xiao LI HaoRan |
| |
| Affiliation: | 1 Department of Chemistry, Shaoxing University, Shaoxing 312000, China; 2 School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, China ;3 Department of Chemistry, Zhejiang University, Hangzhou 310027, China) |
| |
| Abstract: | Macroscopic properties of ionic liquids （ILs） are stemed from their microstructure and interaction, which governed their applications. Spectroscopic technologies have been developed and utilized to probe microscopic environment and interaction of ILs. Recently, spectroscopic methods also have been played important roles on correlation or prediction of macroscopic properties of ILs. In this review, the recent progress in the studies of the relationships between the spectroscopic properties such as IR, Raman, NMR, ESR, and thermodynamic properties of ILs and ILs/solvent mixtures are introduced and reviewed. |
| |
| Keywords: | ionic liquids thermodynamic properties spectroscopic properties correlation |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
